In a buffer solution containing an equal concentration of B- and HB, the Kb for B- is 10-10.The pH of buffer solution is

  • 10

  • 7

  • 6

  • 6


D.

6

For basic buffer

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The ionisation constant of ammonium hydroxide is 1.77 x 10-5 at 298 K. Hydrolysis constant of ammonium chloride is 

  • 5.65 x 10-10

  • 6.50 x 10-12

  • 5.65 x 10-13

  • 5.65 x 10-13


A.

5.65 x 10-10

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The reaction,
2A (g) + B (g)  ⇌ 3C (g) + D (g) 
is begun with the concentrations of A and B both at an initial value of 1.00 M. When equilibrium is reached, the concentration of  D is measured and found to be 0.25 M. The value for the equilibrium constant for this reaction is given by the expression

  • [(0.75)3 (0.25)] / [(1.00)2 (1.00)]

  • [(0.75)3 (0.25) ] / [(0.50)2(0.75)]

  • [(0.75)3(0.25)] / [(0.50)2(0.75)]

  • [(0.75)3(0.25)] / [(0.50)2(0.75)]


B.

[(0.75)3 (0.25) ] / [(0.50)2(0.75)]

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Which of the following molecules acts as a Lewis acid?

  • (CH)3B

  • (CH3)O

  • (CH3)P

  • (CH3)P


A.

(CH)3B

According to Lewis concept " Acids are electron acceptor and bases are electron donor" Since, electron deficient compounds also have an ability to accept electrons, these are regarded as acids.

Trimethylborane (CH)3B have incomplete octet thus, act as Lewis acid.



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Nitrobenzene can be prepared from benzene by using a mixture of conc. HNO3 and Conc. H2SO4.In the mixture, nitric acid acts as a/an:

  • reducing agent

  • acid

  • base

  • base


C.

base

Proton donor is acids and proton acceptor is bases.
Conc. H2SO4 and conc. HNO3 react in the following manner:

HNO3 + H2SO4 → H2NO3+ +HSO4-
H2NO3+ → NO2+ +H2O
Hence, in this reaction HNO3 acts as a base and H2SO4 as an acid.

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